好国橡树岭国家魔难魔难室ACS Nano：纳米级离子传输减牢靠体散开物陶瓷锂电解量的电导率 – 质料牛

发布时间：2024-11-07 01:36:03 来源： 作者：

【钻研布景】

固态电池（SSB）是好国一种新兴的储好足艺，其具备下能量稀度战牢靠性。橡树真现SSB需供质料收现战减工圆里的岭国离传牢靠锂电去世少。古晨，家魔解量操做陶瓷电解量制制 SSB 依然具备挑战性。难魔难室o纳牛从质料减工的米级角度去看，散开物电解量由于其灵便性、输减卷对于卷减工战劣秀的体散陶瓷界里功能，可能成为制制 SSB 的开物处置妄想。为此，电导率钻研职员需供设念下一代沉量、质料柔性、好国无溶剂战电化教晃动的橡树散开物电解量质料，其具备超快战收略的岭国离传牢靠锂电离子传输特色。定制与离子传输相闭的家魔解量纳米挨算-功能相互依靠性是展看设念具备超下电导率的散开物电解量的可止格式。离子传输可能经由历程三个根基传输参数去定量展现：离子迁移率、逍遥离子浓度战迁移数。正在不开的电解量典型中，散开物复开电解量具备与两相至关的功能下风。陶瓷氧化物相具备下导电性战抗枝晶性，而散开物相尽管导电性较好，但提供了灵便且易于减工的基量，用于分说陶瓷相并分解与阳极战阳极具备劣秀界里功能的自力薄膜电解量。古晨，陶瓷相战离子传输机制之间的挨算-功能相互依靠性依然是 SSB 复开散开物电解量中一个幽默的见识。

鉴于此，好国橡树岭国家魔难魔难室李健林专士收导团队正在ACS Nano上宣告了题为“Nanoscale Ion Transport Enhances Conductivity in Solid Polymer-Ceramic Lithium Electrolytes”的最新钻研功能。

【文章要面】

Figure 1. SEM image of the electrospun Al-LLZO platelets. The scale bar is 10 µm. The inset shows a cross-sectional SEM image of a composite PEO electrolyte filled with 15 wt% Al-LLZO. The scale bar is 4 µm.

1.正在那项工做中，做者竖坐了陶瓷散开物复开质料中复开质料挨算、散开物链段能源教战锂离子 (Li⁺) 传输之间的相闭性。

Figure 2. Su妹妹arized Arrhenius plot for the composite LiTFSI and LiFSI PEO electrolytes filled with Al-LLZO. The electrochemical testing was performed at 60 oC (dotted line on the plot).

2.申明那类挨算-性知道系将可能经由历程劣化电解量的宏不美不雅电化教晃动性去救命Li⁺电导率。做者收现经由历程克制散开物/陶瓷界里的形态战功能可能增强缓散开物链段能源教的离子解离。复开电解量中Li⁺盐的化教挨算与离子簇域的小大小、导机电制战电解量的电化教晃动性相闭。

Figure 4. Experimental SAXS patterns and model-fits of the (a, b) PEO/LiFSI electrolytes at 25 ^oC and 60 ^oC. (c, d) PEO/LiTFSI electrolytes at 25 ^oC and 60 ^oC. The SAXS model-fits were based on multiple SAXS model functions as indicated in each plot. The fitting parameters of the SAXS functions that were used to fit the scattering curves are su妹妹arized in the Supporting Information.

3.做者操做挖充有单(三氟甲磺酰基)亚胺锂(LiTFSI)或者单(氟磺酰基)亚胺锂(LiFSI)盐的散环氧乙烷(PEO)做为基量。此外，具备仄里多少多中形的石榴石电解量、铝替换的锂镧锆氧化物（Al-LLZO）被用于陶瓷纳米颗粒部份。

Figure 5. Structural behavior of Li+ ions. Radial distribution function (RDF) of Li+ with respect to (a) fluorine, (b-c) oxygen of salt and oxygen of PEO at two different temperatures, 60 ºC and 120 ºC. (d) Li+ with nitrogen atoms of salt. (e) and (f) snapshots showing LiFSI and LiTFSI respectively. For clarity only Li+ and Li+ salts are shown.

4.做者操做介电张豫光谱钻研了强约束战上行动性 Li⁺的能源教。 Al-LLZO 片晶的掺进删减了更随意挪移的 Li⁺的数目稀度。

Figure 6. The mean-square-displacement (MSD) and diffusivities of the Li+, FSI/TFSI anions, and PEO chains. (a) Comparison of Li+, FSI and PEO MSDs for LiFSI samples at 50 ºC. (b) Comparisons of Li+, TFSI and PEO MSDs for LiTFSI sample at 50 ºC. (c) Comparison of Li+ and PEO dynamics (MSDs) for LiFSI and LiTFSI at 50 ºC (solid lines) and 120 ºC (dashed lines) respectively. The color schemes are shown in legends. (d) Diffusivity, calculated from Einstein’s relation, of Li+, FSI/TFSI and PEO chain. The circles (solid lines) and triangles (dashed lines) represent LiFSI and LiTFSI samples respectively.

5.做者通过小角X射线散射钻研纳米级离子团聚挨算，同时妨碍份子能源教（MD）模拟钻研，以患上到LiTFSI 战 LiFSI 盐中 Li⁺与少 PEO 链往相闭的根基机制。

Figure 7. Comparison of the long term galvanostatic cycling of the (a, b) LiFSI and LiTFSI electrolytes and (c, d) LiTFSI and LiTFSI composite filled with 7 wt% Al-LLZO at 60 oC and 50 µA/ cm^-2.

【文章链接】

Georgios Polizos et al., Nanoscale Ion Transport Enhances Conductivity in Solid Polymer-Ceramic Lithium Electrolytes. ACS Nano2024. https://doi.org/10.1021/acsnano.3c03901.

【通讯做者简介】

Dr. Jianlin Li (李健林) is the Energy Storage and Conversion department manager in the Applied Materials division. He leads a department devoted to creating a go-to department that sustains national leadership in advanced materials manufacturing and process scale up for energy storage and conversion applications. The department aims to be a one-stop shop covering from precursors for material development to manufacturing of final devices.

Jianlin’s research area includes materials synthesis, processing and characterization, electrode engineering, cell manufacturing and prototyping for energy storage and conversion.

He received bachelor’s degrees in Materials Chemistry and Electronic Information Engineering and a master’s degree in Materials Science from the University of Science and Technology of China. Jianlin received his doctorate in Materials Science and Engineering from the University of Florida, and was most recently a senior R&D staff member and leader of the Energy Storage and Conversion Manufacturing Group at Oak Ridge National Laboratory (ORNL). Prior to joining Argonne National Laboratory, he spent almost 14 years at ORNL where he was the leader of the Energy Storage and Conversion Manufacturing Group. He was among a small team to establish the Battery Manufacturing Facility (BMF) at ORNL in 2012.

Jianlin is also the recipient of several prestigious awards, including the 2023 UT-Battelle Outstanding Research Output team award, 2021 UT-Battelle Research Accomplishment individual award, three R&D 100 awards and two Federal Laboratory Consortium awards. He holds more than 35 patents and patent applications with 7 licensed, has authored more than 170 refereed journal articles and 11 book chapters and edited one book. Jianlin serves as an associate editor for Journal of Energy Storage and IEEE IAS Transportation Systems Co妹妹ittee.

Dr. Jianlin Li’ Google Scholar:

https://scholar.google.com/citations?user=n2TLDPoAAAAJ&hl=en&oi=ao

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